Espresso has more caffeine: 63mg per 1 oz shot against 12.4mg per 1 tbsp (5.4g), a gap of 50.6mg. Measured by concentration the order is reversed, at 65.3mg per oz versus 63mg.
Unsweetened cocoa powder vs espresso: the numbers
| Unsweetened cocoa powder | Espresso | |
|---|---|---|
| Caffeine per serving | 12.4mg per 1 tbsp (5.4g) | 63mg per 1 oz shot |
| Caffeine per oz | 65.3mg | 63mg |
| Servings to reach 400mg | 32 | 6 |
| Source | USDA FoodData Central, SR Legacy 169593 (230mg per 100g) | USDA FoodData Central |
Both figures were checked against their source before this page went up: unsweetened cocoa powder against USDA FoodData Central, SR Legacy 169593 (230mg per 100g) (source) and espresso against USDA FoodData Central (source). Brewed drinks and cocoa foods vary by batch, so published figures are averages rather than guarantees. One of these is a food and one is a drink, so the per ounce row weighs an ounce of unsweetened cocoa powder against a fluid ounce of espresso. The per serving row is the one that matches how people actually consume them.
Where the caffeine in unsweetened cocoa powder comes from
Cacao contains caffeine and theobromine, and the caffeine rides along into anything made with real cocoa solids. The more cocoa solids in the product, the more caffeine: unsweetened cocoa powder runs 230mg per 100g, dark chocolate at 70 to 85 percent cacao runs 80mg per 100g, and milk chocolate runs 20mg per 100g, all per USDA FoodData Central. Coffee-flavored desserts are a separate case, because the caffeine comes from actual coffee rather than cacao. Serving size does the rest of the work, which is why a mug and a square of chocolate can land in the same range.
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If you want to control how much cacao goes in the mug, and therefore how much caffeine, start with plain powder instead of a pre-sweetened packet: browse unsweetened cocoa powder on Amazon.
For context, the FDA cites 400mg of caffeine a day as an amount generally not associated with negative effects in healthy adults. Tolerance and health vary, so treat these numbers as information, not advice.
Related reading
- Unsweetened cocoa powder: the full caffeine breakdown
- Espresso: the full caffeine breakdown
- Does decaf have caffeine? Every decaf drink ranked
- Hidden caffeine: the foods and drinks people forget to count
- The verified caffeine database
- Compare any two drinks side by side
FAQ
Does unsweetened cocoa powder or espresso have more caffeine? Espresso, at 63mg per 1 oz shot against 12.4mg per 1 tbsp (5.4g) for unsweetened cocoa powder.
How much caffeine is in unsweetened cocoa powder? 12.4mg per 1 tbsp (5.4g), which works out to about 65.3mg per oz. The figure comes from USDA FoodData Central, SR Legacy 169593 (230mg per 100g).
Is unsweetened cocoa powder caffeine free? No. Unsweetened cocoa powder carries 12.4mg per 1 tbsp (5.4g). It is a small amount, but small is not the same as none.
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